详细介绍:
PEI 基础创新塑料(美国) 2400-7301 BK,价格合理,诚信经营,可全国供货(广东省内免费送上门)。支持物流,快递和货运;支持现金,银行转账交易。
东莞市广业塑胶原料有限公司专业销售原装进口塑胶原料,原厂原包,假一赔十,本司货源稳定充足,发货准时,交期和质量均有保障!是专业塑胶原料供应商!!!可提供COA,SMDS,SGS,COC,UL黄卡和物性表及加工参数。
PEI 基础创新塑料(美国) 2400-7301 BK特性:
PEI基础创新塑料(美国)2400-7301 BK增强级耐高温
PEI 基础创新塑料(美国)
2400-7301 BK
PEI 基础创新塑料(美国)
2400-7301 BK
PEI 基础创新塑料(美国)
2400-7301 BK
PEI 基础创新塑料(美国)
2400-7301 BK
PEI 基础创新塑料(美国)
2400-7301 BK
PEI 基础创新塑料(美国) 2400-7301 BK 其他型号报价:
在380℃下熔融挤出制得聚醚醚酮(PEEK)与聚醚酰亚胺(PEI)共混物。采用差示扫描量热仪(DSC)和广角x射线衍射仪(WAXD)研究了共混物的相容性和结晶行为。结果表明,PEEK/PEI共混物完全相容.所有共混物均呈现一个玻璃化转变温度(r, ),且与组分的关系符合Porch方程;随PEI含量的增加,共混体系的熔点、结晶度、整体结晶速率和结晶能力均降低:而PEEK的结晶度呈现先增加后减小的趋势,
当PEI质量分数为50%时,达到最大。
聚醚醚酮(PEEK)和聚醚酰亚胺(PEI)都是高性能聚合物,具有较高的耐热温度和优异的机械性能u J,作为工程塑料广泛应用于各领域 J。PEEK为半结晶性材料,其玻璃化转变温度( )为150 oC,熔点为340 oC左右,因此需要在较高的温度下进行加工,一般为370~400 oC。PEI是一种无定形材料,相对高的 (215 oC)和优异的机械性质是其优点;但由于PEI的耐溶剂性能相对较差,使其在工业应用领域,特别是航空应用方面受到限制 J。共混是开发新材料的一个重要方法,高分子混合物可以通过简便的方法得到,而所得的材料却具有混合组分所没有的综合性能l4 J。因此,将PEEK与PEI共混可以使二者的性质相互补充,对充分发挥材料的性能并拓宽应用范围有着现实的意义。但国内对PEEK/PEI共混物报道甚少。本文通过熔融挤出制得PEEK/PEI共混物,主要分析研究了两者的相容性和结晶行为,并采用一种简便的方法比较了不同组成共混物的结晶速率和结晶能力。
1 实验部分
1.1 主要原料及仪器
聚醚醚酮(PEEK):粉末状, 粒径500目,长春吉大高新材料公司;聚醚酰亚胺(PEI):Uheml000,颗粒状,GE公司。
差示扫描量热仪(DSC):DSC 204F1,德国耐驰公司;x射线衍射仪(WAXD):D8
Advance型,德国Bruker公司。
1.2 PEEK/PEI共混物的制备
将PEEK和PE1分别放于120℃烘箱中烘l h,然后按质量比(100/0,75/25,50/50,25/75和0/100)准确称量,熔融挤出,挤出温度为380℃ ,制得不同比例的PEEK/PEI共混物。
1.3 性能测试
DSC测试:吹扫气和保护气均为高纯氮气,流量分别为20 mL/min和60 mL/min;升温速率为10℃/min;样品量为5~10 mg。WAXD 测试:cu靶80。。
所有共混物均只检测到一个 ,表明该共混体系完全相容。这与PE1的结构有关,在PEI的酰亚胺基与对苯基间存在电荷转移相互作用。在PEEK/PEI共混物分子间的这种电荷转移相互作用有两种类型 5 J:一种是PEI和PE1分子间的作用(酰亚胺是电子受体,对苯基是电子给体);另一种是PEI与PEEK分子间的相互作用(PEI的对苯基是电子受体,PEEK的对苯基是电子给体)。这两类相互作用彼此竞争,如果后一类相互作用比前一类强,则共混物相容;反之,不相容。另外,通过引入某些柔顺链节将分子链中两相邻酐环分离开,通常是降低一部分酐的电子亲和力。由于PEI二酐的长度较长,相应酐的部分亲和力较弱,即PEEK/PEI共混物PEEK与PEI间的相互作用占主导地位,
因而此共混体系是相容的。
,纯PEEK在升温过程中未出现结晶峰,而共混物均有结晶峰出现。这是由于PEI的加入使共混物的整体结晶能力和结晶速率降低,在熔体冷却过程中结晶不完全,
因此在升温过程中发生再结晶;且随PEI用量的增加,共混物的 . 高,链段需要在更高的温度下才能发生运动,因而结晶也需在更高的温度下进行,从而使. 随PEI的增加而升高。
PEI 基础创新塑料(美国) 2400-7301 BK
PEI
|
基础创新塑料(美国)
|
2400
|
120000
|
PEI
|
基础创新塑料(美国)
|
2400-7301
|
50000
|
PEI
|
基础创新塑料(美国)
|
2400-7301 BK
|
115000
|
PEI
|
基础创新塑料(美国)
|
2410-7301
|
115000
|
PEI
|
基础创新塑料(美国)
|
2412-1000
|
116000
|
PEI
|
基础创新塑料(美国)
|
2412EPR-1000
|
115000
|
PEI
|
基础创新塑料(美国)
|
3451-7301
|
115000
|
PEI
|
基础创新塑料(美国)
|
3452-1000
|
115000
|
PEI
|
基础创新塑料(美国)
|
3452-701
|
115000
|
PEI
|
基础创新塑料(美国)
|
4000-7401
|
10000
|
PEI
|
基础创新塑料(美国)
|
4001-1001
|
120000
|
PEI
|
基础创新塑料(美国)
|
4001-1100
|
100000
|
PEI
|
基础创新塑料(美国)
|
4001-7402
|
75000
|
PEI
|
基础创新塑料(美国)
|
4211-7401
|
150000
|
PEI
|
基础创新塑料(美国)
|
6202-1000
|
100000
|
PEI
|
基础创新塑料(美国)
|
8015-7147
|
60000
|
PEI
|
基础创新塑料(美国)
|
8015-81004
|
99000
|
PEI
|
基础创新塑料(美国)
|
8015-8114
|
99000
|
PEI
|
基础创新塑料(美国)
|
8015-BR3218
|
99000
|
PEI
|
基础创新塑料(美国)
|
801-7701
|
110000
|
PEI 基础创新塑料(美国) 2400-7301 BK
Polyetherimide,
Polyetherimide referred to as PEI [1], is an amber transparent solid, without
adding any additives have inherent flame retardancy and low smoke, oxygen index
of 47%, combustion grade UL94-V-0 , The density is 1.28 ~ 1.42g / cm3. PEI has
a strong high temperature stability, even non-enhanced PEI, still has a good
toughness and strength. So the use of PEI superior thermal stability can be
used to make high-temperature heat-resistant devices. With excellent mechanical
properties, electrical insulation properties, radiation resistance, high and
low temperature resistance and wear resistance, and through the microwave. PEI
also has good flame resistance, chemical resistance and electrical insulation
properties. Glass transition temperature is high, up to 215 ℃. PEI also has a
very low shrinkage and good mechanical properties in the same direction. Adding
glass fiber, carbon fiber or other filler can achieve the purpose of enhancing
the modification; can also be composed of other engineering plastics heat
polymer alloy, can be -160 ~ 180 ℃ operating temperature long-term use.
The US
Underwriters Laboratories have specified that the long-term use temperatures of
the polyether imide resins are 338T and 356T (depending on the grade) and the
combustion rating is UL94V-0 (10 mil thickness). The oxygen index reaches 47,
and the polyetherimide meets the aircraft Pieces of FAA required for flame
retardancy and heat radiating material standards. Its glass transition
temperature is 419F and is allowed to be intermittently used at 392F, resulting
in short-term shifts at higher temperatures. At 356T, the stretching
temperature and flexural modulus were above 41 and 2068 MPa, respectively. With
glass fiber, carbon fiber reinforced materials have a higher strength and
stiffness near glass transition temperature.
The long-term
creep resistance of polyether imides at high temperatures and stresses allows
them to replace metal and other materials in many structural equipment. In the
variable temperature, moisture and frequency conditions show good electrical
properties. The low loss factor at the GHz frequency gives the polyetherimide a
high microwave wearability. Its ionic contaminants are low in the range of
250F100% R. H. And 207 kPa 120 hours after the extraction of water
conductivity, more than 20 megohm, it can be used as an insulating material for
electronic sensor components.
Polyether imide
is an excellent coating and film-forming material that can form coatings and
films suitable for use in the electronics industry and can be used to produce
microporous membranes with a pore size of <0.1μm and a high permeability.
Can also be used as high temperature adhesives and high strength fibers.
PEI board is
non-crystalline plastic. Is an amorphous high-performance polymer, is made of
amorphous PEI (polyether imide) made of engineering plastics extruded through
the extruder at high temperature.
Because PEI has
excellent comprehensive balance performance, it is used effectively in the
industrial sectors such as electronics, motor and aviation, and used as a
substitute for traditional products and cultural life of metal materials. The
use of PEI instead of metal manufacturing fiber optic connectors, can optimize
the structure of components, simplify its manufacturing and assembly steps, to
maintain a more accurate size. For use in the automotive field, such as sensors
(air conditioning temperature sensors) for controlling the external temperature
of the car compartment and sensors (effective combustion temperature sensors)
for controlling the temperature of the air and fuel mixture, for the
manufacture of high temperature connections, high power lights and indicator
lights. Can also be used as a high temperature resistant oil erosion of the
vacuum pump impeller, 180 ° C operation of the burner of the grinding glass
connector (socket), non-illuminated anti-fog lamp reflector.
如需了解更多关于PEI 基础创新塑料(美国) 2400-7301 BK及 的详细信息,欢迎致电联系。
零风险购货10天无理由退换货
为了更好的服务客户,我公司现推出零风险采购方案,你在我公司购买的货物只要发货后10天内。你对货物有任何不满意都可以提出退换申请,在货物未拆封,不影响二次销售的情况下,我司将给你办理退换手续并承担运费,为你免去任何担忧。
PEI 基础创新塑料(美国) 2400-7301 BK
|